5-(3,6-Dibromo-9H-carbazol-9-yl)pentanenitrile

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5-(3,6-Dibromo-9H-carbazol-9-yl)penta­nenitrile

In the title compound, C(17)H(14)Br(2)N(2), the carbazole skeleton is nearly planar [maximum deviation = 0.055 (2) Å]. In the crystal, aromatic π-π stacking is observed between parallel carbazole ring systems of adjacent mol-ecules, the shortest centroid-centroid distance between benzene rings being 3.4769 (11) Å.

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(9H-Carbazol-9-ylmeth­yl)diethyl­amine

The asymmetric unit of the title compound, C(17)H(20)N(2), contains two mol-ecules, whose bond lengths and angles differ only slightly. In the crystal, neighbouring mol-ecules form pillar structures via edge-to-face π-π stacking inter-actions [edge-to-face distances = 3.538 (3) and 3.496 (3)Å].

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2,5-Bis(9H-carbazol-9-yl)thio­phene

The mol-ecules of the title compound, C(28)H(18)N(2)S, are built up from two triply-fused rings and one five-membered ring, with dihedral angles of 66.12 (8) and 70.96 (7)° between the central thio-phene ring and the two triply-fused rings.

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Crystal structure of poly[[[μ4-5-(9H-carbazol-9-yl)isophthalato][μ3-5-(9H-carbazol-9-yl)isophthalato]bis­(di­methyl­formamide)(methanol)dizinc] di­methyl­formamide monosolvate]

The structure of the polymeric title compound, {[Zn2(C20H11NO4)2(C3H7NO)2(CH3OH)]·C3H7NO} n , comprises carbazolylisophthalate moieties connecting dimetallic tetra-carboxyl-ate zinc secondary building units (SBUs) parallel to [100] and [010], leading to a layer-like arrangement parallel to (001). Each SBU consists of two Zn atoms in slightly distorted tetra-hedral and octa-hedral coordination e...

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3,6-Dibromo-9-(4-chloro­benz­yl)-9H-carbazole

The title compound, C(19)H(12)Br(2)ClN, was synthesized by N-alkyl-ation of 1-chloro-4-(chloro-meth-yl)benzene with 3,6-dibromo-9H-carbazole. The carbazole ring system is essentially planar (mean deviation of 0.028 Å) and makes a dihedral angle of 74.6 (3)° with the plane of the benzene ring.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811005162